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002711

002711-5g



N-Bromosuccinimide


CAS Number: 128-08-5
   
Molecular Formula: C4H4BrNO2
   
Molecular Weight: 177.99
   
MDL Number: MFCD00005510


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002711-5g
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002711-25g
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002711-50g
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002711-100g
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002711-500g
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002711-1kg
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Purity:98%
Mp:180-183°
 
Pictograms:
Signal Word:Danger
Hazard Statements:H314, H318
Precautionary Statements:P280, P310, P305 + P351 + P338
UN#:UN3261
Packing Group:II
Hazard Class:8
SDS: See MSDS
 
Limited Quantities:1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid)
Excepted Quantities:Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)

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NBS is a brominating and oxidizing agent that is used as source for bromine in radical reactions and various electrophilic additions. A major use is in the bromination of allylic or benzylic positions in substrates.1,2 Other potential uses are bromination of activated benzene rings, cleavage of benzyl ethers and esters, conversion of alcohols to alkyl bromides, and oxidation of certain reactive substrates. 3,4,5
1. Org. Lett. 2009, 11, 465.
2. Synlett 2006, 1269.
3. Synthesis 2004, 1741.
4. Synthesis 2009, 306.
5. Org. Lett. 2007, 9, 3809.

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