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011742

011742-5g



FMOC-ONSU


CAS Number: 82911-69-1
   
Molecular Formula: C19H15NO5
   
Molecular Weight: 337.331
   
MDL Number: MFCD00010733


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011742-5g
Regular Price: $10.00
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011742-10g
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011742-25g
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011742-100g
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011742-250g
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011742-1Kg
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Purity:99%
Mp:150-153°
 
Pictograms:
Signal Word:Warning
Hazard Statements:H302, H315, H317, H319, H335, H401, H411
Precautionary Statements:P261, P273, P280, P301 + P312, P302 + P352, P305 + P351 + P338, P330, P333 + P313, P391
UN#:UN3077
Packing Group:III
Hazard Class:9
SDS: See MSDS
 
Limited Quantities:5.0 L (1.3 gallons) (liquid) or 5.0 kg (11 lbs) (solid)
Excepted Quantities:Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)

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Reagent for the protection with the Fmoc group. Most efficient reagent for the selective preparation of N-(9-fluorenylmethoxycarbonyl) derivatives of hydroxy-amino acids in high yield.1,2  Dipeptide formation is lower than with the chloroformate, Fmoc-Cl.3  Employed in the synthesis of glycopeptides and large-scale syntheses of Fmoc-protected non-proteogenic amino acids.4 Lately contaminants Fmoc-b-Ala-OH and Fmoc-b-Ala-AA-OH were found in commercial Fmoc amino acids prepared with Fmoc-Osu.5

1. Org. Prep. Proced. Int. 199830, 183.
2. Bull. Korean Chem. Soc. 2005, 26, 175.
3. Pept. Sci. 2007, 88, 733.
4. Org. Proc. Res. Dev. 2001, 5, 44.
5. J. Pept. Sci. 2008, 14, 763.

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