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009019

009019-5g



HBTU


CAS Number: 94790-37-1
   
Molecular Formula: C11H16F6N5OP
   
Molecular Weight: 379.24
   
MDL Number: MFCD00075445


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009019-5g
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009019-25g
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009019-100g
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009019-500g
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009019-1kg
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009019-5Kg
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Purity:99%
Mp:203°(dec.)
 
Pictograms:
Signal Word:Warning
Hazard Statements:H315, H317, H319, H334, H335
Precautionary Statements:P261, P301 + P312, P302 + P352, P304 + P340, P305 + P351 + P338
SDS: See MSDS
 

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The more cost effective alternative to HATU and one of the most popular in situ activation reagents in solid and solution phase peptide synthesis that have high reactivity with simple reaction conditions, short reaction time and limit enantiomerization during fragment condensation and during DMAP catalyzed esterification of arginine derivatives 1,2,3,4. But lower yielding couplings can become problematic on industrial scales and with long peptides. HBTU activation has been adapted for automated stepwise solid-phase peptide synthesis for both t-butoxycarbonyl (Boc) and fluorenylmethoxycarbonyl(Fmoc) strategies 5. Also a convenient agent for the synthesis of tetramethylsulfonylguanidines in basic conditions 6.
1. J. Comb. Chem. 2004, 6, 695
2. Org. Bio. Chem2010, 8, 835
3. Biopoly. 2006, 84, 340
4. Ukr. Bioorg. Acta 2004, 1, 23
5. Pept Res. 1991, 4, 95
6. Tetrahedron Lett. 2006, 47, 6087

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