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LIMITED EDITION MAGNETS







005264

005264-5g



tert-Butyldiphenylchlorosilane

CAS Number: 58479-61-1
   
Molecular Formula: 58479-61-1
   
Molecular Weight: 274.87
   
MDL Number: MFCD00000497

Special Handling and Safety: Hazardous for shipment
tert-Butyldiphenylchlorosilane
(98%)

Purity:98%
Bp:90-92°/0.01mm
Density:1.057
Refractive Index:1.5680
 
Pictograms:
Signal Word:Danger
Hazard Statements:H314, H318
Precautionary Statements:P280, P301 + P330 + P331, P303 + P361 + P353, P304 + P340, P305 + P351 + P338, P310
UN#:UN2987
Packing Group:II
Hazard Class:8
Flash Point:112°
SDS:
 
Excepted Quantities:Not Permitted as Excepted Quantity

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A Reagent to introduce the tert-butyldiphenylsilyl (TBDPS) group that is an exceedingly sterically hindered hydroxyl protecting group, especially in the protection of alcohols.1 The t–butyldiphenylsilyl protecting group is considerably more stable (approximately 100 times) than the t–butyldimethylsilyl protecting group toward acidic hydrolysis.1 Applied in a variety of complex natural product syntheses.2,3,4

1. Protective Groups in Organic Synthesis, 3rd Edition 1999, 141
2. Resonance 2002, 7(12), 48.
3. J. Phys. Chem. B 2004, 108, 12640.
4. Chin. Chem. Lett. 2000, 11, 883.

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005264-5g
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tert-Butyldiphenylchlorosilane

CAS Number: 58479-61-1
   
Molecular Formula: 58479-61-1
   
Molecular Weight: 274.87
   
MDL Number: MFCD00000497

Special Handling and Safety: Hazardous for shipment
tert-Butyldiphenylchlorosilane
(98%)

Purity:98%
Bp:90-92°/0.01mm
Density:1.057
Refractive Index:1.5680
 
Pictograms:
Signal Word:Danger
Hazard Statements:H314, H318
Precautionary Statements:P280, P301 + P330 + P331, P303 + P361 + P353, P304 + P340, P305 + P351 + P338, P310
UN#:UN2987
Packing Group:II
Hazard Class:8
Flash Point:112°
SDS:
 
Excepted Quantities:Not Permitted as Excepted Quantity

Enter Lot No:


Submit
A Reagent to introduce the tert-butyldiphenylsilyl (TBDPS) group that is an exceedingly sterically hindered hydroxyl protecting group, especially in the protection of alcohols.1 The t–butyldiphenylsilyl protecting group is considerably more stable (approximately 100 times) than the t–butyldimethylsilyl protecting group toward acidic hydrolysis.1 Applied in a variety of complex natural product syntheses.2,3,4

1. Protective Groups in Organic Synthesis, 3rd Edition 1999, 141
2. Resonance 2002, 7(12), 48.
3. J. Phys. Chem. B 2004, 108, 12640.
4. Chin. Chem. Lett. 2000, 11, 883.

Enter Lot No:


Submit

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