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022072

022072-5g



Fmoc-chloride


CAS Number: 28920-43-6
   
Molecular Formula: C15H11ClO2
   
Molecular Weight: 258.71
   
MDL Number: MFCD00001138


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022072-5g
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022072-10g
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022072-25g
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022072-100g
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022072-500g
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Purity:98%
Mp:62-64°
 
Pictograms:
Signal Word:Danger
Hazard Statements:H314, H318
Precautionary Statements:P280, P301 + P330 + P331, P302 + P352, P304 + P340, P305 + P351 + P338, P310
UN#:UN3261
Packing Group:II
Hazard Class:8
RTECS:LQ6250000
SDS: See MSDS
 
Limited Quantities:1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid)
Excepted Quantities:Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)

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A chloroformate ester. Reagent for introducing Fmoc group. For preparing N-Fmoc amino acids in solid-phase peptide synthesis by reaction with the amine.1,2 Also used to synthesis of Fmoc-Osu by  the reaction with the dicyclohexylammonium salt of N-hydroxysuccinimide.3 Reagent for derivatizing amino acids for HPLC amino acid analysis4,5 and for for the pre-column fluorescent derivatization of amino acids.6,7

1. Tetrahedron Lett. 2001, 42, 2587.
2. ARKIVOC 2008 (ii) 243.
3. Int. J. Pept. Protein Res. 1985, 27, 398.
4. J. Chromatogr. B 2007, 860, 42.
5. Chirality 2007, 20, 63.
6. Chromatographia 1997, 46, 245.
7. J. Chromatogr. A 2001, 938, 15.

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