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003409

003409-1g



1,1,1,3,3,3-Hexafluoro-2-propanol


CAS Number: 920-66-1
   
Molecular Formula: C3H2F6O
   
Molecular Weight: 168.04
   
MDL Number: MFCD00011651


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003409-1g
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003409-5g
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003409-10g
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003409-25g
Regular Price: $15.00
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003409-50g
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003409-100g
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003409-250g
Regular Price: $40.00
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003409-500g
Regular Price: $75.00
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003409-1kg
Regular Price: $130.00
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003409-2.5Kg
Regular Price: $325.00
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003409-5Kg
Regular Price: $650.00
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003409-25kg
Regular Price: $3,250.00
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Purity:99.5%
Bp:59-60°
Mp:-4°
Density:1.596
Refractive Index:1.2750
 
Pictograms:
Signal Word:Danger
Hazard Statements:H302, H314, H318, H361
Precautionary Statements:P201, P262, P264, P280, P301 + P312, P301 + P330 + P331, P303 + P361 + P353, P304 + P340, P305 + P351 + P338, P308 + P313, P310
UN#:UN3265
Packing Group:II
Hazard Class:8
RTECS:UB6450000
SDS: See MSDS
 
Limited Quantities:1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid)
Excepted Quantities:Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)

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A speciality solvent for polar polymers and organic synthesis.1,2 It has also found use in biochemistry to solubilize peptides and and peptide intermediates with high solubilizing potential.3,4 It’s been used in the absence of catalysts to allow electrophilic activation of hydrogen peroxide toward epoxidation of alkenes and the Baeyer−Villiger oxidation of ketones.5 Employed as a fluorinated solvent to enhance the efficiency of rhodium(I)-catalyzed [4+2] intramolecular cycloaddition of ether-tethered alkynyl dienes and [5+2] cycloaddition of alkynyl vinylcyclopropanes.6

1. Synthesis 2004, 18.
2. Synthesis 2007, 2925.
3. Biochemistry 1990, 29, 2639
4. Tetrahedron Lett. 1995, 36, 7833.
5. Org. Lett.2000, 2, 2861.
6. J. Org. Chem. 2006, 71, 6437.

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